1609583-89-2Relevant academic research and scientific papers
Synthesis of tertiary allylboronates from vinylboronates
Ondrusek, Brian A.,Park, Jin Kyoon,McQuade, D. Tyler
supporting information, p. 239 - 242 (2014/02/14)
Allylic boronates are versatile intermediates in organic synthesis. Herein, we present an 'ate-mediated allylic substitution' (AMAS) approach to allylic boronates. Bifunctional vinylboroate/ allylic acetate esters react with Grignard reagents to form tertiary allylic boronates via an AMAS reaction. We demonstrate that the method tolerates a wide range of substrates and Grignard reagents. Georg Thieme Verlag Stuttgart New York.
