1609646-75-4Relevant academic research and scientific papers
Ru(ii)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)-H activation
Liu, Bingxian,Li, Bin,Wang, Baiquan
supporting information, p. 16334 - 16337 (2015/11/17)
Ru(ii)-catalyzed amidation reactions of 8-methylquinolines with azides have been developed. They are the first examples of [(p-cymene)RuCl2]2-catalyzed C(sp3)-H bond intermolecular amidation reactions which give quinolin-8-ylmethanamines under mild reaction conditions in good yields.
Rhodium(III)-catalyzed intermolecular amidation with azides via C(sp 3)-H functionalization
Wang, Nuancheng,Li, Renhe,Li, Liubo,Xu, Shansheng,Song, Haibin,Wang, Baiquan
, p. 5379 - 5385 (2014/06/23)
The amidation reactions of 8-methylquinolines with azides catalyzed by a cationic rhodium(III) complex proceed efficiently to give quinolin-8- ylmethanamine derivatives in good yields via C(sp3)-H bond activation under external oxidant-free conditions. A catalytically competent five-membered rhodacycle has been isolated and characterized, revealing a key intermediate in the catalytic cycle.
