1609938-87-5Relevant articles and documents
Five-coordinate MII-semiquinonate (M = Fe, Mn, Co) complexes: Reactivity models of the catechol dioxygenases
Wang, Peng,Yap, Glenn P.A.,Riordan, Charles G.
supporting information, p. 5871 - 5873 (2014/05/20)
A series of five-coordinate MII-semiquinonate (M = Fe, Mn, Co) complexes were synthesized and characterized, including the first example of a mononuclear FeII-semiquinonate. Intermediates were observed in the reactions of MII-phenSQ (M = Fe, Co) with O2. Evidence for the relevance of these intermediates to the intradiol catechol dioxygenases was obtained by characterization of the oxidized semiquinone-derived product, muconic anhydride, resulting from the reaction of [PhTttBu]Co II(3,5-DBSQ) with O2. This journal is the Partner Organisations 2014.
