1609945-91-6

Basic information

• Product Name: cis-1-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)-(2R)-benzoyl-(3R)-(4-nitrophenyl)aziridine
• Synonyms: cis-1-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)-(2R)-benzoyl-(3R)-(4-nitrophenyl)aziridine
• CAS NO: 1609945-91-6
• Molecular Weight: 766.886
• Mol File: 1609945-91-6.mol

Chemical Properties

• CAS DataBase Reference: cis-1-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)-(2R)-benzoyl-(3R)-(4-nitrophenyl)aziridine(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)-(2R)-benzoyl-(3R)-(4-nitrophenyl)aziridine(1609945-91-6)
• EPA Substance Registry System: cis-1-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)-(2R)-benzoyl-(3R)-(4-nitrophenyl)aziridine(1609945-91-6)

Safety Data

• Hazardous Substances Data: 1609945-91-6(Hazardous Substances Data)

Upstream product

• 1196447-20-7 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine 
• 3282-32-4 2-diazo-acetophenone 

Relevant articles and documents

Diastereoselective formation of aziridines from diazocarbonyl compounds and N-(O-pivaloylated d-galactosyl)benzylideneamines and ring-opening reactions with p-toluenethiol

N-Galactosyl aziridines were synthesized via BF3·OEt 2 promoted addition of carbenes generated from diazocarbonyl compounds with O-pivaloylated β-d-galactosylimines in good yields and high diastereoselectivity. The ring-opening reactions with p-toluenethiol of the aziridines provided enantiometrically pure β-S-substituted phenylalanine derivatives in a highly regioselective manner. the Partner Organisations 2014.