1610026-36-2Relevant academic research and scientific papers
Palladium-catalyzed regioselective azidation of allylic C-H bonds under atmospheric pressure of dioxygen
Chen, Huoji,Yang, Wanfei,Wu, Wanqing,Jiang, Huanfeng
, p. 3340 - 3343 (2014/05/20)
A palladium-catalyzed allylic azidation of alkenes with sodium azide under atmospheric pressure of dioxygen was developed. This methodology provides a new efficient and simple route for accessing allylic azides. Furthermore, the one-pot process consisting of Pd-catalyzed allylic azidation of alkenes and Cu-catalyzed 1,3-dipolar cycloaddition led directly to the 1,2,3-triazole from the alkene. The formed allylic azide can be also in situ reduced to the allylic amine or oxidized to the alkenyl nitrile. the Partner Organisations 2014.
