161009-86-5Relevant academic research and scientific papers
Synthesis of Medium Ring Azacycles via Allene-based Cyclizations: Evaluation of Possible Mechanistic Pathways
Davies, Ian W.,Shaw, Robert W.,Wisedale, Richard,Gallagher, Timothy
, p. 3557 - 3562 (2007/10/02)
Two pathways have been evaluated to account for the I2-mediated cyclisation of the allenic sulfonamides 1a-e based on (i) the steric demands of the allenic unit, and (ii) the ambident reactivity of the sulfonamide anion.The 1,3-disubstituted allenic sulfo
