161013-76-9Relevant academic research and scientific papers
Some peculiarities of the preparative electroreduction of allyldimethylsulfonium salts
Korotaeva, L. M.,Rubinskaya, T. Ya.,Gultyai, V. P.
, p. 1191 - 1196 (1994)
The influenece of electrode potential and (6-acetoxy-1-isopropenyl-4-methylhexyl)dimethylsulfonium perchlorate concentration on the yield of α-citronellyl acetate and the selectivity of reduction were studied.A mechanism of electrolytic reduction involving preparative electrolysis on a mercury cathode at potentials of the first and second waves was proposed. - Key words: electrolytic reduction; mercury cathode; allyldimethylsulfonium salts; α-citronellyl acetate.
