1610462-60-6

Basic information

• Product Name: (E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1610462-60-6
• Molecular Weight: 356.011
• Mol File: 1610462-60-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1610462-60-6)
• EPA Substance Registry System: (E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1610462-60-6)

Safety Data

• Hazardous Substances Data: 1610462-60-6(Hazardous Substances Data)

Upstream product

• 173603-23-1 (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) 
• 536-74-3 phenylacetylene 
• 73183-34-3 bis(pinacol)diborane 

Relevant articles and documents

Solvent-and ligand-free diboration of alkynes and alkenes catalyzed by platinum nanoparticles on titania

Platinum nanoparticles supported on titania efficiently catalyzed the diboration of alkynes and alkenes under solvent-and ligand-free conditions in air. The cis-1,2-diborylalkenes and 1,2-diborylalkanes were obtained in moderate to excellent yields following, in most cases, a simple filtration workup protocol. The versatility of the cis-1,2-diboronvinyl compounds was demonstrated in a series of organic transformations, including the Suzuki-Miyaura cross coupling and the boron-halogen exchange. Click diboration: The diboration of alkynes and alkenes catalyzed by platinum nanoparticles on titania is shown to take place under solvent-and ligand-free conditions in air. The 1,2-diboronvinyl compounds are obtained with exclusive cis stereochemistry and are subjected to different useful chemical transformations.