1610475-26-7Relevant articles and documents
Stabilisation of 2,6-diarylpyridinium cation by through-space polar-π interactions
Padial, Joan Simo,Degelder, Rene,Fonsecaguerra, Celia,Bickelhaupt, F. Matthias,Mecinovic, Jasmin
supporting information, p. 6268 - 6271 (2014/06/09)
The through-space polar-π interactions between pyridinium ion and the adjacent aromatic rings in 2,6-diarylpyridines affect the pKavalues. Hammett analysis illustrates that the basicity of pyridines correlates well with the sigma values of the