1610699-04-1

Basic information

• Product Name: benzyl (R)-3-(1-methyl-1H-indol-3-yl)-3-(2-nitroethyl)-2-oxoindoline-1-carboxylate
• CAS NO: 1610699-04-1
• Molecular Weight: 469.497
• Mol File: 1610699-04-1.mol

Chemical Properties

• CAS DataBase Reference: benzyl (R)-3-(1-methyl-1H-indol-3-yl)-3-(2-nitroethyl)-2-oxoindoline-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (R)-3-(1-methyl-1H-indol-3-yl)-3-(2-nitroethyl)-2-oxoindoline-1-carboxylate(1610699-04-1)
• EPA Substance Registry System: benzyl (R)-3-(1-methyl-1H-indol-3-yl)-3-(2-nitroethyl)-2-oxoindoline-1-carboxylate(1610699-04-1)

Safety Data

• Hazardous Substances Data: 1610699-04-1(Hazardous Substances Data)

Upstream product

• 3638-64-0 1-nitroethylene 
• 1610698-85-5 C₂₅H₂₀N₂O₃ 

Relevant articles and documents

An imidazoline-aminophenol (IAP) nickel catalyst: Structure and catalytic activity in the enantioselective 1,4-addition of 3′-indolyl-3-oxindoles to nitroethylene

The structure of a nickel complex of imidazoline-aminophenol (IAP) prepared from IAP with Ni(OAc)2 was elucidated as cis- bis(imidazolineaminophenoxide) [Ni(IAP)2]. The [Ni(IAP)2] complex smoothly promoted catalytic asymmetric 1,4-addition of 3′-indolyl-3-oxindole to nitroethylene to provide chiral mixed 3,3′-bisindoles with high enantioselectivities. Mechanistic studies using ESI-MS analyses suggest that one IAP ligand dissociated from [Ni(IAP) 2] to generate the Ni-enolate of 3′-indolyl-3-oxindole. From the optically active 3,3′-mixed indole adduct, biologically important 3′-indolyl-3-pyrrolidinoindoline was successfully synthesized in a three-step reaction sequence. Copyright