1610768-63-2Relevant articles and documents
Base-promoted aryl-bromine bond cleavage with cobalt(ii) porphyrins via a halogen atom transfer mechanism
Liu, Chun Ran,Qian, Ying Ying,Chan, Kin Shing
, p. 7771 - 7779 (2014/05/20)
Aryl-bromine bonds are successfully cleaved by cobalt(ii) porphyrins in basic media to give Co(por)Ar (por = porphyrin) in good yields. Mechanistic studies suggested that the aryl-bromine bond is cleaved through a halogen atom transfer mechanism, which is different from the aryl-halogen bond cleavage mechanism with other group 9 metalloporphyrins. This journal is the Partner Organisations 2014.