1610879-79-2Relevant academic research and scientific papers
Addition of optically pure H-phosphinate to ketones: Selectivity, stereochemistry and mechanism
Sun, Yong-Ming,Xin, Nana,Xu, Zhong-Yuan,Liu, Li-Juan,Meng, Fan-Jie,Zhang, He,Fu, Bao-Ci,Liang, Qiu-Ju,Zheng, Hong-Xing,Sun, Li-Jun,Zhao, Chang-Qiu,Han, Li-Biao
supporting information, p. 9457 - 9465 (2014/12/11)
Aromatic methyl ketones and cyclic asymmetric ketones underwent hydrophosphorylation with P-stereogenic H-P species in the presence of potassium carbonate to produce P,C-stereogenic tertiary α-hydroxyl phosphinates in excellent yields with up to 99 : 1 dr
Stereogenic phosphorus-induced diastereoselective formation of chiral carbon during nucleophilic addition of chiral H-P species to aldehydes or ketones
Zhang, He,Sun, Yong-Ming,Yao, Lan,Ji, Si-Yu,Zhao, Chang-Qiu,Han, Li-Biao
supporting information, p. 1329 - 1333 (2014/05/06)
P,C-Stereogenic α-hydroxyl phosphinates or phosphine oxides were prepared from the additions of (RP)-phosphinate to ketones or (R P)-phosphine oxide to aldehydes, respectively, catalyzed by bases at room temperature in up to >99:1 di
