16109-39-0Relevant academic research and scientific papers
PHOTOCHEMISTRY OF DIBENZO-1,1,2,2,3,3-HEXAMETHYL-1,2,3-TRISILACYCLOHEPTA-4,6-DIENE AND THE GERMANIUM ANALOG. GENERATION OF TETRAMETHYLDISILENE BY FREE-RADICAL DISPROPORTIONATION AND THE FIRST SPECTROSCOPIC DETECTION OF DIMETHYLGERMYLENE
Sakurai, Hideki,Sakamoto, Kenkichi,Kira, Mitsuo
, p. 1379 - 1382 (2007/10/02)
Photolysis of the title compound afforded silafluorene and dibenzo-1,2-disilacyclohexadiene as primary photoproducts.Two reactive intermediates, tetramethyldisilene and dimethylsilylene, were trapping.The dimethylgermylene, derived from germanium analog, was first observed by electronic spectra.
REACTIONS OF SILYLENES WITH 1,4-DIPHENYL-1,3-BUTADIENE AND 1-METHYL-1,2,3,4,5-PENTAPHENYLSILOLE. A NOVEL SILYLENE-SILYLENE EXCHANGE REACTION
Sakurai, Hideki,Kobayashi, Yoshiteru,Sato, Ryuji,Nakadaira, Yasuhiro
, p. 1197 - 1200 (2007/10/02)
Thermally generated dimethylsilylene reacts with 1,4-diphenyl-1,3-butadiene to give 1,1-dimethyl-4,5-diphenyl-1-silacyclo-2-pentene.A mechanism involving homolytic C-C bond cleavage of the intermediate vinylsilacyclopropane is suggested.Dimethylsilylene also undergoes a novel silylene-silylene exchange reaction with 1-methyl-1,2,3,4,5-pentaphenylsilole.
