1611528-11-0Relevant articles and documents
Intramolecular π stacking in cationic iridium(III) complexes with phenyl-functionalized cyclometalated ligands: Synthesis, structure, photophysical properties, and theoretical studies
Li, Peng,Shan, Guo-Gang,Cao, Hong-Tao,Zhu, Dong-Xia,Su, Zhong-Min,Jitchati, Rukkiat,Bryce, Martin R.
, p. 2376 - 2382 (2014)
The syntheses of two new heteroleptic cationic iridium complexes containing 2,6-diphenylpyridine (Hdppy) and 2,4,6-triphenylpyridine (Htppy) as the cyclometalated ligands, namely, [Ir(dppy)2phen]PF6 (1, phen = 1,10-phenanthroline) and [Ir(tppy)2phen]PF6 (2), are described. The X-ray crystal structure of 2 reveals a distorted octahedral geometry around the Ir center and close intramolecular face-to-face π-π stacking interactions between the pendant phenyl rings at the 2-position of the cyclometalated ligands and the NN ancillary ligand. This represents a new π-π stacking mode in charged Ir complexes. Complexes 1 and 2 are green photoemitters: their photophysical and electrochemical properties are interpreted with the assistance of density functional theory (DFT) calculations. These calculations also establish that the observed intramolecular interactions cannot effectively prevent the lengthening of the Ir-N bonds of the complexes in their metal-centered (3MC) states. Complexes 1 and 2 do not emit light in light-emitting electrochemical cells (LECs) under conditions in which the model compound [Ir(ppy)2phen]PF6 (3) emits strongly. This is explained by degradation reactions of the 3MC state of 1 and 2 under the applied bias during LEC operation facilitated by the enhanced distortions in the geometry of the complexes. These observations have important implications for the future design of complexes for LEC applications. A combined experimental and theoretical study of the cationic iridium complexes [Ir(dppy)2phen]PF6 (1) and [Ir(tppy)2phen]PF6 (2) is described. The complexes are green photoemitters. Strong intramolecular π-π stacking leads to enhanced distortions in the geometry of the complexes, which is detrimental to their use in light-emitting electrochemical cells (LECs).
