161155-36-8Relevant articles and documents
Synthesis, transformations, and physicochemical properties of nitro derivatives of 1H,4H-pyrazolopyrazole
Shevelev, S.A.,Dalinger, I.L.,Shkineva, T.K.,Ugrak, B.I.,Gulevskaya, V.I.,Kanishchev, M.I.
, p. 1063 - 1068 (2007/10/02)
A method of synthesizing nitro derivatives of 1H,4H-pyrazolopyrazole is developed, and some of its transformations are studied. 3-Methyl-6-nitro-, 3-carboxy(methoxycarbonyl, carbamoyl)-6-nitro-, 3-amino-6-nitro-, 3-nitro-, 3,6-dinitro-, 1,4-diacetonyl-3,6-dinitro-, and 1H,4H-3-aminopyrazolopyrazoles were obtained from 1H,4H-3-methylpyrazolopyrazole.Unsubstituted 1H,4H-pyrazolopyrazole, the first member of this series, was obtained for the first time.The compounds prepared were characterized by 1H, 13C, 14N, and 15N NMR spectroscopy.NH-Acidity and basicity of the series of pyrazolopyrazoles ...