1612146-89-0

Basic information

• Product Name: 1-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione
• Synonyms: 1-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione
• CAS NO: 1612146-89-0
• Molecular Weight: 510.497
• Mol File: 1612146-89-0.mol

Chemical Properties

• CAS DataBase Reference: 1-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione(1612146-89-0)
• EPA Substance Registry System: 1-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione(1612146-89-0)

Safety Data

• Hazardous Substances Data: 1612146-89-0(Hazardous Substances Data)

Upstream product

• 1612146-88-9 1-(6-hydroxybenzo[d][1,3]dioxol-5-yl)-2-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)phenyl]ethane-1,2-dione 
• 107-30-2 chloromethyl methyl ether 
• 1612146-87-8 methyl 6-[4-(4-methoxybenzyloxy)-2-(methoxymethoxy)benzyloxy]benzo[d][1,3]dioxole-5-carboxylate 

Downstream Products

• 1612146-90-3 1-[4-hydroxy-2-(methoxymethoxy)phenyl]-2-[6-(methoxymethoxy)-benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione 
• 1612146-91-4 1-[2-(methoxymethoxy)-4-(2-methylbut-3-yn-2-yloxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione 
• 1612146-92-5 1-[2-(methoxymethoxy)-4-(2-methylbut-3-en-2-yloxy)phenyl]-2-[6-(methoxymethoxy)benzo[d][1,3]dioxol-5-yl]ethane-1,2-dione 
• 1612146-95-8 C₂₄H₂₆O₉ 
• 1612146-94-7 C₂₂H₂₂O₈ 

Relevant articles and documents

Total synthesis of unsymmetrical benzils, scandione and calophione A

The synthesis of the title unsymmetrical benzils, scandione and calophione A, is described. The key processes involve intramolecular cyclization reaction of the carbanion at the benzylic position of the arylbenzyl ether to the adjacent ester group followed by oxidation. The palladium(II)-catalyzed oxidative cyclization was also used to establish the benzofuran unit of calophione A. A convergent synthesis of the title benzils, which embody the 1,2-diarylethane-1,2-dione system, is reported. Key steps involve intramolecular cyclization of the carbanion at the benzylic position of the arylbenzyl ether to the adjacent ester group followed by oxidation. The palladium(II)-catalyzed oxidative cyclization was also studied to establish the benzofuran unit of calophione A. Copyright