1612760-03-8

Basic information

• Product Name: 1-(2-fluorophenyl)ethan-1-one-O-acetyl oxime
• Synonyms: 1-(2-fluorophenyl)ethan-1-one-O-acetyl oxime
• CAS NO: 1612760-03-8
• Molecular Weight: 195.193
• Mol File: 1612760-03-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(2-fluorophenyl)ethan-1-one-O-acetyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-fluorophenyl)ethan-1-one-O-acetyl oxime(1612760-03-8)
• EPA Substance Registry System: 1-(2-fluorophenyl)ethan-1-one-O-acetyl oxime(1612760-03-8)

Safety Data

• Hazardous Substances Data: 1612760-03-8(Hazardous Substances Data)

Upstream product

• 364-81-8 2'-fluoroacetophenone oxime 
• 108-24-7 acetic anhydride 
• 445-27-2 2'-Fluoroacetophenone 

Downstream Products

• 1519051-02-5 N'-(2-fluorophenyl)-N-phenylacetimidamide 
• 1492822-28-2 1-(2-fluorophenyl)-2-p-toluenesulfonyl ethanone 

Relevant articles and documents

Copper(0)/PPh3-Mediated Bisheteroannulations of o-Nitroalkynes with Methylketoximes Accessing Pyrazo-Fused Pseudoindoxyls

A copper(0)/PPh3-mediated cascade bisheteroannulation reaction of o-nitroalkynes with methylketoximes has been developed that provides viable access to a diverse range of pyrazo-fused pseudoindoxyl compounds. Synthetically useful functional groups including sensitive C-I bonds are compatible with this system. Mechanistic studies suggest a reaction cascade involving sequential PPh3-mediated deoxygenative cycloisomerization and copper-catalyzed [3 + 2] pyrazo-annulation.