1612778-26-3Relevant academic research and scientific papers
Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids
Wangweerawong, Apiwat,Hummel, Joshua R.,Bergman, Robert G.,Ellman, Jonathan A.
, p. 1547 - 1557 (2016/03/01)
A high yielding and practical two-step synthesis of enantiomerically pure perfluorobutanesulfinamide from Senanayake's 2-aminoindanol-derived sulfinyl transfer reagent was developed and carried out on a multigram scale. Straightforward condensation of thi
Asymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization
Wangweerawong, Apiwat,Bergman, Robert G.,Ellman, Jonathan A.
supporting information, p. 8520 - 8523 (2014/07/07)
The first asymmetric intermolecular addition of non-acidic C-H bonds to imines is reported. The use of the activating N-perfluorobutanesulfinyl imine substituent is essential for achieving sufficient reactivity and provides outstanding diastereoselectivit
