Welcome to LookChem.com Sign In|Join Free

CAS

  • or

1613-51-0

Post Buying Request

1613-51-0 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

1613-51-0 Usage

Uses

It is a useful 5 c synthon for the synthesis of 3-cyclopentenones. It is a organic sulfide, that has shown to have antioxidant activity.

Synthesis Reference(s)

Synthesis, p. 540, 1978 DOI: 10.1055/s-1978-24806

Check Digit Verification of cas no

The CAS Registry Mumber 1613-51-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,6,1 and 3 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1613-51:
(6*1)+(5*6)+(4*1)+(3*3)+(2*5)+(1*1)=60
60 % 10 = 0
So 1613-51-0 is a valid CAS Registry Number.
InChI:InChI=1/C5H10S/c1-2-4-6-5-3-1/h1-5H2

1613-51-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L03063)  Tetrahydrothiopyran, 98%   

  • 1613-51-0

  • 1g

  • 217.0CNY

  • Detail
  • Alfa Aesar

  • (L03063)  Tetrahydrothiopyran, 98%   

  • 1613-51-0

  • 5g

  • 601.0CNY

  • Detail

1613-51-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Thiane

1.2 Other means of identification

Product number -
Other names dihydro-thiopyran

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1613-51-0 SDS

1613-51-0Relevant articles and documents

Ring closure of 2-thia- and 2-sulfonyl-5-hexenyl radicals

Della,Graney

, p. 7987 - 7990 (2000)

Reductive cyclisation of the 2-sulfonyl-5-hexenyl radical with tributyltin hydride in benzene at 80°C affords a 73:23 mixture of the sulfones derived from 5-exo- and 6-endo- ring closure with a small quantity (4%) of reduced material; under identical conditions, the 2-thia-5-hexenyl radical gives a 70:13:17 mixture of the corresponding sulfides. (C) 2000 Elsevier Science Ltd.

Synthesis, structure, and reactions of a copper-sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)

Zhai, Junjie,Filatov, Alexander S.,Hillhouse, Gregory L.,Hopkins, Michael D.

, p. 589 - 595 (2015/12/26)

The synthesis of the first CuI2(μ-S) complex, {(IPr?)Cu}2(μ-S) (IPr? = 1,3-bis(2,6-(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene; 1), has been accomplished via three synthetic routes: (1) salt metathesis between (IPr?)CuCl and Na2S; (2) silyl-deprotection reaction between (IPr?)Cu(SSiMe3) and (IPr?)CuF; and (3) acid-base reaction between (IPr?)Cu(SH) and (IPr?)Cu(OtBu). The X-ray crystal structure of 1 exhibits two two-coordinate copper centers connected by a bent Cu-S-Cu linkage. Application of these synthetic routes to analogous precursors containing the sterically smaller ligand IPr (1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidene), in place of IPr?, resulted in the formation of a transient product proposed as {(IPr)Cu}2(μ-S) (2), which decomposes quickly in solution. The instability of 2 probably results from the insufficient steric protection provided by IPr ligands to the unsaturated Cu2(μ-S) core; in contrast, 1 is stable both in solution and solid state for weeks. The nucleophilic sulfido ligand in 1 reacts with haloalkyl electrophiles (benzyl halides and dibromoalkanes) with formation of C-S bonds, affording (IPr?)Cu(SCH2Ph) and cyclic thioethers, respectively.

Synthesis of 3,6-diaryl-1,4,5-thiadiazepines from substituted 2-thiocyano acetophenone and investigation of reaction mechanism

Rahimizadeh,Feizyzadeh,Bakavoli,Eshghi

, p. 276 - 283 (2013/08/26)

In this work, we have studied the reaction of substituted 2-thiocyanoacetophenone and hydrazine hydrate as a novel and simple pathway for the preparation of the substituted 1,4,5-thiodiazepine ring system. The mechanism of this reaction revealed that in the initial step condensation of hydrazine with carbonyl groups of substituted 2-thiocyanoacetophenons 2a-2f gives the corresponding substituted aromatic dithiocyano azide intermediates which in turn undergo cyclization to1,4,5-thiadiazepines in the presence of hydrazine. This cyclization is a novel method for the preparation of sulfide bond from the reaction of hydrazine and a dithiocyano intermediate. An account of the reaction mechanism is given.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1613-51-0