1613059-32-7

Basic information

• Product Name: (S)-3-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2-(hydroxymethyl)propyl 4-(dimethylamino)benzoate
• Synonyms: (S)-3-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2-(hydroxymethyl)propyl 4-(dimethylamino)benzoate
• CAS NO: 1613059-32-7
• Molecular Weight: 383.56
• Mol File: 1613059-32-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2-(hydroxymethyl)propyl 4-(dimethylamino)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2-(hydroxymethyl)propyl 4-(dimethylamino)benzoate(1613059-32-7)
• EPA Substance Registry System: (S)-3-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2-(hydroxymethyl)propyl 4-(dimethylamino)benzoate(1613059-32-7)

Safety Data

• Hazardous Substances Data: 1613059-32-7(Hazardous Substances Data)

Upstream product

• 111160-83-9 tert-butyldimethyl(2-methylallyloxy)silane 
• 1613059-49-6 2-(((tert-butyldimethylsilyl)oxy)methyl)allyl 4-(dimethylamino)benzoate 
• 619-84-1 p-N,N-dimethylaminobenzoic acid 
• 116700-73-3 2-(tert-butyl-dimethyl-silanyloxymethyl)-prop-2-en-1-ol 

Relevant articles and documents

N,N-Dimethylaminobenzoates enable highly enantioselective Sharpless dihydroxylations of 1,1-disubstituted alkenes

A design scenario aimed at exploring beneficial catalyst-substrate π-π stacking electronic interactions in the classical Sharpless asymmetric dihydroxylations (SAD) leads to the identification of highly polarizable allylic N,N-dimethylaminobenzoate as a remarkably efficient auxiliary for inducing high levels of enantioselectivities (up to 99% ee) in the traditionally challenging substrate class of 1,1-disubstituted aliphatic alkenes. the Partner Organisations 2014.