1613416-90-2

Basic information

• Product Name: (E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol
• Synonyms: (E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol
• CAS NO: 1613416-90-2
• Molecular Weight: 276.443
• Mol File: 1613416-90-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol(1613416-90-2)
• EPA Substance Registry System: (E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol(1613416-90-2)

Safety Data

• Hazardous Substances Data: 1613416-90-2(Hazardous Substances Data)

Upstream product

• 1415351-98-2 (E)-S-4-cyclohexylbut-3-en-2-yl 1H-imidazole-1-carbothioate 
• 1613417-21-2 (E)-S-4-cyclohexyl-2-(3-methoxyphenyl)but-3-en-2-yl methylcarbamothioate 
• 1613417-04-1 (E)-S-4-cyclohexylbut-3-en-2-yl 3-methoxyphenyl(methyl)carbamothioate 
• 18736-82-8 1-cyclohexyl-but-2-en-1-ol 

Downstream Products

• 1613416-63-9 (S)-2-(3-methoxyphenyl)-2-methyl-2,5-dihydrothiophene 
• 1613416-62-8 2-(3-methoxyphenyl)-2-methyl-2,5-dihydrothiophene 
• 1613416-76-4 (E)-allyl(4-cyclohexyl-2-(3-methoxyphenyl)but-3-en-2-yl)sulfane 

Relevant articles and documents

Dihydrothiophenes containing quaternary stereogenic centres by sequential stereospecific rearrangements and ring-closing metathesis

Stereospecific [3,3]-sigmatropic rearrangement of O-substituted thiocarbamate derivatives of enantiopure allylic alcohols provides allylic thiocarbamates as single enantiomers. Intramolecular arylation by rearrangement of their allyllithium derivatives provides allylic tertiary thiols. Allylation and ring-closing metathesis gives 2,5-dihydrothiophenes containing sulfur-bearing quaternary centres. This journal is the Partner Organisations 2014.