1613439-86-3

Basic information

• Product Name: N-(3-(N,N-dimethylaminocarbonylphenyl))-2-(2-naphthyl)-2-oxoacetamide
• CAS NO: 1613439-86-3
• Molecular Weight: 346.386
• Mol File: 1613439-86-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(3-(N,N-dimethylaminocarbonylphenyl))-2-(2-naphthyl)-2-oxoacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-(N,N-dimethylaminocarbonylphenyl))-2-(2-naphthyl)-2-oxoacetamide(1613439-86-3)
• EPA Substance Registry System: N-(3-(N,N-dimethylaminocarbonylphenyl))-2-(2-naphthyl)-2-oxoacetamide(1613439-86-3)

Safety Data

• Hazardous Substances Data: 1613439-86-3(Hazardous Substances Data)

Upstream product

• 14289-45-3 2-(naphthalen-2-yl)-2-oxoacetic acid 
• 73790-09-7 ethyl 2-naphthylglyoxylate 
• 580-13-2 2-bromonaphthalene 
• 33322-60-0 3-amino-N,N-dimethylbenzamide 

Relevant articles and documents

Cationic Ir/Me-BIPAM-catalyzed asymmetric intramolecular direct hydroarylation of α-ketoamides

Asymmetric intramolecular direct hydroarylation of α-ketoamides gives various types of optically active 3-substituted 3-hydroxy-2-oxindoles in high yields with complete regioselectivity and high enantioselectivities (84-98 % ee). This is realized by the use of the cationic iridium complex [Ir(cod) 2](BArF4) and the chiral O-linked bidentate phosphoramidite (R,R)-Me-BIPAM. Carbon's got a brand new bond: Asymmetric intramolecular direct hydroarylation of α-ketoamides gives various optically active 3-substituted 3-hydroxy-2-oxindoles in high yields with complete regioselectivity and high enantioselectivities. This is realized by the use of an asymmetric cationic iridium complex formed in situ (see Scheme).