1613472-73-3Relevant academic research and scientific papers
Highly enantioselective kinetic resolution of axially chiral BINAM derivatives catalyzed by a Bronsted acid
Cheng, Dao-Juan,Yan, Liang,Tian, Shi-Kai,Wu, Ming-Yue,Wang, Lu-Xin,Fan, Zi-Li,Zheng, Sheng-Cai,Liu, Xin-Yuan,Tan, Bin
, p. 3684 - 3687 (2014)
A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Bronsted acid-catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities. Chiral BINAMs on demand: A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Bronsted acid catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities.
