1613546-85-2Relevant academic research and scientific papers
Synthesis, structure and reactivity of [o-(2,6- diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (RSeSeCN) and related derivatives
Rakesh, Prakul,Singh, Harkesh B.,Jasinski, Jerry P.,Golen, James A.
, p. 9431 - 9437 (2014/06/23)
The synthesis and the first X-ray structural characterization of a selenenyl selenocyanate, [o-(2,6-diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (DiPhSeSeCN), with a stable Se-Se bond are described. The isolation of stable DiPhSeSeCN, both in the solid state and in solution, is facilitated by strong intramolecular Se...N interaction. The compound DiPhSeSeCN, an example of unsymmetrical diselenide, did not exhibit any glutathione peroxidase-like activity. The reaction of DiPhSeSeCN with thiophenol afforded (3H-benzo[c][1,2]diselenol-3-yl)(phenyl)sulfane.
