1613753-22-2Relevant academic research and scientific papers
PHOSPHINE-OLEFIN LIGAND HAVING FACE ASYMMETRIC CYCLOPENTADIENYL-MANGANESE COMPLEX IN BASIC SKELETON
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Paragraph 0087; 0098, (2017/06/27)
PROBLEM TO BE SOLVED: To provide a face asymmetric ligand for a transition metal catalyst asymmetric reaction high in yield and optical purity to not only a cyclic enone compound, but also various enone compounds containing an aliphatic enone compound. SO
Phosphine-olefin ligands based on a planar-chiral (π-Arene)chromium scaffold: Design, synthesis, and application in asymmetric catalysis
Ogasawara, Masamichi,Tseng, Ya-Yi,Arae, Sachie,Morita, Tomotaka,Nakaya, Takeshi,Wu, Wei-Yi,Takahashi, Tamotsu,Kamikawa, Ken
supporting information, p. 9377 - 9384 (2014/07/21)
The NMR and X-ray crystallographic studies clarified that planar-chiral alkenylene-bridged (phosphino-π-arene)(phosphine)chromium complexes 3 were capable of coordinating to a rhodium(I) cation in a bidentate fashion at the (π-arene)-bound phosphorus atom
