161436-20-0

Basic information

• Product Name: Benzene,4-[(2E)-3-fluoro-2-propen-1-yl]-1,2-dimethoxy-
• Synonyms: Benzene,4-(3-fluoro-2-propenyl)-1,2-dimethoxy-, (E)-; Benzene,4-[(2E)-3-fluoro-2-propenyl]-1,2-dimethoxy- (9CI)
• CAS NO: 161436-20-0
• Molecular Formula: C₁₁H₁₃FO₂
• Molecular Weight: 196.2181
• Mol File: 161436-20-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 258.1°Cat760mmHg
• Flash Point: 117.1°C
• Density: 1.055g/cm³
• CAS DataBase Reference: Benzene,4-[(2E)-3-fluoro-2-propen-1-yl]-1,2-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,4-[(2E)-3-fluoro-2-propen-1-yl]-1,2-dimethoxy-(161436-20-0)
• EPA Substance Registry System: Benzene,4-[(2E)-3-fluoro-2-propen-1-yl]-1,2-dimethoxy-(161436-20-0)

Safety Data

• Hazardous Substances Data: 161436-20-0(Hazardous Substances Data)

Relevant articles and documents

Monofluoro analogs of eugenol methyl ether as novel attractants for the oriental fruit fly

Monofluoro analogs of eugenol methyl ether as potential attractants for the Oriental fruit fly (Bactrocera dorsalis, Hendel) were synthesized using selective fluorination reactions: electrophilic hydro- and iodofluorination, fluorodehydroxylation with (diethylamido)sulfur trifluoride (DAST), and Wittig fluoroolefination through the stabilized ylides. Unusual reduction of the double bond was detected in a reaction of eugenol methyl ether with pyridinium poly(hydrogen fluoride). Bis[(3,4-dimethoxyphenyl)alkyl] carbonates were identified as the novel nucleophilic substitution products of the intermediate generated from the reaction of 3,4-dimethoxybenzenealkanols with DAST. Reductive desulfonylation of fluorovinyl sulfone 24-(Z) with sodium amalgam afforded 1,2-dimethoxy-4-(3-fluoro-2-propenyl)benzene (E/Z = 85: 15) which was highly attractive to the Oriental fruit fly.