161458-75-9

Basic information

• Product Name: (7S,8S)-(-)-2-Methyl-7-(p-toluenesulfonyloxy)-8-acetoxyoctadecane
• Synonyms: (7S,8S)-(-)-2-Methyl-7-(p-toluenesulfonyloxy)-8-acetoxyoctadecane
• CAS NO: 161458-75-9
• Molecular Weight: 496.752
• Mol File: 161458-75-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (7S,8S)-(-)-2-Methyl-7-(p-toluenesulfonyloxy)-8-acetoxyoctadecane(CAS DataBase Reference)
• NIST Chemistry Reference: (7S,8S)-(-)-2-Methyl-7-(p-toluenesulfonyloxy)-8-acetoxyoctadecane(161458-75-9)
• EPA Substance Registry System: (7S,8S)-(-)-2-Methyl-7-(p-toluenesulfonyloxy)-8-acetoxyoctadecane(161458-75-9)

Safety Data

• Hazardous Substances Data: 161458-75-9(Hazardous Substances Data)

Upstream product

• 161458-74-8 (4S,5S)-(-)-1-Iodo-4-hydroxy-10-methyl-5-(p-toluenesulfonyloxy)undecane 
• 1028277-25-9 (2S,1'S)-(-)-2-<1-(p-Toluenesulfonyloxy)-6-methylheptyl>tetrahydrofuran 
• 1025945-38-3 (2S,1'S)-(-)-2-(1-Hydroxy-6-methylheptyl)-2,5-dihydrofuran 
• 1027017-07-7 (2S,1'S)-(-)-2-(1-Hydroxy-6-methylheptyl)tetrahydrofuran 
• 113466-79-8 4-methylpentyllithium 
• 25047-67-0 n-heptyllithium 
• 1025937-18-1 (4S,5S)-(-)-1-Iodo-4-acetoxy-10-methyl-5-(p-toluenesulfonyloxy)undecane 

Downstream Products

• 54910-51-9 (2S-cis)-7,8-epoxy-2-methyloctadecane 

Relevant articles and documents

Dihydro- and Tetrahydrofuran Building Blocks from 1,4:3,6-Dianhydrohexitols. 2. Synthesis of Acetal, Alcohol, Diol, Epoxide, Hydrocarbon, and Lactone Pheromones

The potential of building blocks 1-3 for synthesis of enantiopure substances is illustrated by their transformation to various insect pheromones featuring functionalities specified in the title.A convenient synthesis of building block 3 from sorbitol is described.