16146-60-4Relevant articles and documents
Synthesis of α-tocopherol analogs with unsaturated side chain and their transformation into the corresponding chromans with ω-functionalized side chain
Odinokov,Spivak,Emelianova,Kutepov,Khalilov
, p. 2227 - 2230 (2001)
α-Tocopherol analogs with double bond-containing side chains were synthesized by condensation of trimethylhydroquinone with optically active (3R/S,4S)-3,4,8-trimethylnona1,7-dien-3-ol and linalool in the presence of the zeolite-containing Tseokar-10 aluminosilicate. Ozonolysis of these compounds gave the corresponding chromans with ω-formyl or (after hydride reduction) ω-hydroxyl groups in the side chain.
Synthesis of α-tocopherol and naphthotocopherol analogs with a carboxyl group in the side chain
Spivak,Knyshenko,Mallyabaeva,Odinokov
, p. 306 - 311 (2007/10/03)
On the basis of ozonolysis of short-chain α-tocopherol and naphthotocopherol analogs with a terminal isopropylidene group in the side chain, a general approach to the synthesis of 6-hydroxy-2,5,7,8- tetrtamethylchroman-2-yl-and 6-hydroxy-2,5-dimethyl-3,4-