1615677-54-7

Basic information

• Product Name: (Z)-ethyl 2-[(tert-butylimino)(cyano)methyl]-4,5-dimethylbenzoate
• Synonyms: (Z)-ethyl 2-[(tert-butylimino)(cyano)methyl]-4,5-dimethylbenzoate
• CAS NO: 1615677-54-7
• Molecular Weight: 286.374
• Mol File: 1615677-54-7.mol

Chemical Properties

• CAS DataBase Reference: (Z)-ethyl 2-[(tert-butylimino)(cyano)methyl]-4,5-dimethylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-ethyl 2-[(tert-butylimino)(cyano)methyl]-4,5-dimethylbenzoate(1615677-54-7)
• EPA Substance Registry System: (Z)-ethyl 2-[(tert-butylimino)(cyano)methyl]-4,5-dimethylbenzoate(1615677-54-7)

Safety Data

• Hazardous Substances Data: 1615677-54-7(Hazardous Substances Data)

Upstream product

• 119072-55-8 tert-butylisonitrile 
• 623-49-4 ethyl cyanoformate 
• 458566-99-9 4,5-dimethyl-2-(trimethylsilyl)phenyl triflate 
• 1449007-87-7 N-[3-cyano-3-ethoxy-5,6-dimethyl-1(3H)-isobenzofuranylidene]-2-methyl-2-propanamine 

Relevant articles and documents

New entry to the synthesis of α-iminonitriles by Lewis acid mediated isomerization of cyano-substituted iminoisobenzofurans prepared by palladium-catalyzed three-component coupling of arynes, isocyanides, and cyanoformates

A variety of α-iminonitriles were formed as the minor products of three-component coupling reactions of arynes, isocyanides, and cyanoformates in the presence of the cationic palladium complex [Pd(NCPh)2(dppf)] (BF4)2 as the catalyst, along with cyano-substituted iminoisobenzofurans as the major products. α-Iminonitriles obtained from this process are hardly accessible by conventional methods. In addition, when the isolated iminoisobenzofurans were treated with diisobutylaluminum hydride (DIBAL-H) or AlMe3, the transformation of cyano-substituted iminoisobenzofurans into α-iminonitriles was observed.