1616251-27-4

Basic information

• Product Name: 1-deoxy-1-[(S_S,1S,2S,5R)-2-isopropyl-5-methylcyclohexylsulfinyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose
• CAS NO: 1616251-27-4
• Molecular Weight: 430.606
• Mol File: 1616251-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-deoxy-1-[(S_S,1S,2S,5R)-2-isopropyl-5-methylcyclohexylsulfinyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-deoxy-1-[(S_S,1S,2S,5R)-2-isopropyl-5-methylcyclohexylsulfinyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose(1616251-27-4)
• EPA Substance Registry System: 1-deoxy-1-[(S_S,1S,2S,5R)-2-isopropyl-5-methylcyclohexylsulfinyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose(1616251-27-4)

Safety Data

• Hazardous Substances Data: 1616251-27-4(Hazardous Substances Data)

Upstream product

• 1616251-22-9 1-deoxy-1-[(1S,2S,5R)-2-isopropyl-5-methylcyclohexylsulfanyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose 
• 38084-03-6 (3aR,5aR,8aR,8bS)-3a-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran 
• 20880-92-6 2,3;4,5-di-O-isopropylidene-β-D-fructopyranose 

Relevant articles and documents

Synthesis and oxidation of thioglicosides underlain by neomenthanethiol, D-glucose, and D-fructose

Synthesis of sulfides proceeding from neomenthanethiol, 1,2-O-isopropylidene-α-D-glucofuranose and 2,3:4,5-di-O-isopropylidene- β-D-fructopyranose was performed to get 65 and 54% yield respectively. Oxidation of the sulfides afforded diastereomeric sulfoxides in the yields from 40 to 53%, and diastereomeric excess (de) up to 36%. After removing the isopropylidene protection from 1-deoxy-1-[(1S,2S,5R)-2-isopropyl-5- methylcyclohexylsulfanyl]-2,3:4,5-di-O-isopropylidene-β-D-fructopyranose a water-soluble sulfide was obtained.