161634-50-0Relevant academic research and scientific papers
Diastereoselectivity in the O-H insertion reactions of rhodium carbenoids derived from phenyldiazoacetates of homochiral alcohols
Aller,Cox,Miller,Moody
, p. 5949 - 5952 (2007/10/02)
Rhodium(II) acetate catalysed decomposition of the phenyldiazoacetates 3 in the presence of alcohols (methanol, propan-2-ol, tert-butanol) led to the O-H insertion products 4 - 6 in varying yields; the diastereomeric excess of the product ranged from 5-53%.
