161638-00-2

Basic information

• Product Name: methyl 4-tert-butyldiphenylsilyloxy-3-hydroxy-2-methylenebutanoate
• Synonyms: methyl 4-tert-butyldiphenylsilyloxy-3-hydroxy-2-methylenebutanoate
• CAS NO: 161638-00-2
• Molecular Weight: 384.547
• Mol File: 161638-00-2.mol

Chemical Properties

• CAS DataBase Reference: methyl 4-tert-butyldiphenylsilyloxy-3-hydroxy-2-methylenebutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-tert-butyldiphenylsilyloxy-3-hydroxy-2-methylenebutanoate(161638-00-2)
• EPA Substance Registry System: methyl 4-tert-butyldiphenylsilyloxy-3-hydroxy-2-methylenebutanoate(161638-00-2)

Safety Data

• Hazardous Substances Data: 161638-00-2(Hazardous Substances Data)

Upstream product

• 145365-08-8 (Z)-2,2,11,11-tetramethyl-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodec-6-ene 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 115869-43-7 (tert-butyldiphenylsilanyloxy)acetaldehyde 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 161638-04-6 6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-5-methylene-[1,3]dioxane-4-carbonitrile 
• 161638-03-5 4-(tert-Butyl-diphenyl-silanyloxy)-2-methylene-3-trimethylsilanyloxy-butyraldehyde 
• 161638-02-4 4-(tert-Butyl-diphenyl-silanyloxy)-2-methylene-3-trimethylsilanyloxy-butan-1-ol 
• 201670-68-0 4-(tert-Butyl-diphenyl-silanyloxy)-3-methanesulfonyloxy-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-butyric acid methyl ester 
• 161638-01-3 4-(tert-Butyl-diphenyl-silanyloxy)-2-methylene-3-trimethylsilanyloxy-butyric acid methyl ester 
• 201670-57-7 4-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-2-[2-((1S,4aS,4bR,8aR,10aR)-2,4b,8,8,10a-pentamethyl-1,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydro-phenanthren-1-yl)-ethyl]-butyric acid methyl ester 

Relevant articles and documents

Synthesis of tricyclopolyprenols via a radical addition and a stereoselective elimination, part II: (Z)-tricyclopentaprenol, (E,E)- and (Z,Z)-tricyclohexaprenol, (Z,Z,Z)-tricycloheptaprenol

Four tricyclopolyprenols have been synthesised by addition of the isocopalenyl radical either to a 2-methylene-3-hydroxy alkenenitrile (in the case of (E,E)-tricyclohexaprenol) or to a methyl 2-methylene-3-hydroxy alkenoate (in the case of the three (Z)-t

The asymmetric Baylis-Hillman reaction as a template in organic synthesis

The Bayils-Hillman reaction of camphor-based acrylates has been demonstrated to result in the formation of products with high optical purity. A model that explains these results and the use of these products in the formation of anti aldol adducts is discu

An unexpected reversal of stereochemistry in a modification of the Rychnovsky cyanohydrin alkylation

Alkylation of cyanohydrin 1,3-acetonides with unsaturated substitution at the 2-position is described. The stereochemistry of the products obtained from this reaction was opposite to that anticipated.