1616494-69-9Relevant academic research and scientific papers
Enantioselective phospha-Michael addition of diarylphosphines to β,γ-unsaturated α-ketoesters and amides
Chew, Renta Jonathan,Teo, Kai Yuan,Huang, Yinhua,Li, Bin-Bin,Li, Yongxin,Pullarkat, Sumod A.,Leung, Pak-Hing
supporting information, p. 8768 - 8770 (2014/07/22)
An enantioselective hydrophosphination of β,γ-unsaturated α-ketoesters and amides has been developed using a chiral palladacycle catalyst. Adducts can be obtained in excellent yields and enantioselectivities, providing direct access to chiral tertiary phosphines which are synthetically useful intermediates in the preparation of bidentate ligands.
