161664-93-3

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 161664-92-2 octyl 2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 10022-13-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose 
• 161664-91-1 octyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 111-87-5 octanol 

Downstream Products

• 1169770-91-5 octyl 2-deoxy-2-phthalimido-3-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-4,6-O-benzylidene-β-D-glucopyranoside 
• 161664-95-5 octyl 4-O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 161664-96-6 octyl 4-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 145064-89-7 octyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside-ethyl 3',4',6'-tri-O-benzyl-1'-thio-α-D-mannopyranoside-2',4-isopropylidene acetal 
• 161664-78-4 octyl 4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 145064-88-6 octyl 4,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 459170-27-5 octyl 4-O-benzoyl-2,6-dideoxy-6-phenylseleno-2-phthalimido-β-D-glucopyraniside 
• 459170-62-8 C₂₆H₃₉NO₈Se 
• 459170-28-6 octyl 3,4-di-O-acetyl-2,6-dideoxy-2-acetamido-6-phenylseleno-β-D-glucopyranoside 
• 503602-58-2 octyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->4)-2-acetamido-6-O-benzyl-2-deoxy-3-O-dibenzylphosphono-β-D-glucopyranoside 
• 503602-54-8 octyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->4)-2-acetamido-6-O-benzyl-2-deoxy-3-O-dibenzylphosphityl-β-D-glucopyranoside 
• 503602-46-8 octyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->4)-3-O-allyl-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 503602-47-9 octyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->4)-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 503602-44-6 octyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl-(1->4)-3-O-allyl-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Relevant academic research and scientific papers

Fluoridolysis of 5,6-epoxy carbohydrates: application to the synthesis of 5-fluoro lactosamine and isolactosamine glycosides

The synthesis of 6-selenophenyl derivatives of β-1,3 and β-1,4 disaccharides has been explored for the purpose of extending our epoxide fluoridolysis methodology to the synthesis of 5-fluoro analogues of N-acetyl isolactosamine (isoLacNAc, lacto-N-biose) and N-acetyl lactosamine (LacNAc) glycosides. Successful synthesis of the C-6 selenium-containing disaccharides was achieved via Lewis acid-mediated donor and acceptor substrates, the latter containing a selectively protected C-6 hydroxyl group for ultimate conversion to the desired 6-selenophenyl disaccharides. In contrast, the use of selenium-containing acceptor substrates under a variety of conditions failed to yield the desired selenium-containing disaccharides. Oxidation of the 6-selenophenyl derivatives to the corresponding selenoxides followed by thermal elimination yielded the exocyclic olefins, which were converted to the 5,6-epoxides. Epoxide fluoridolysis yielded the desired target compounds, 5-fluoro β-octyl glycoside analogues of type 1 and type 2 glycans. The newly synthesized fluorine-containing disaccharides have potential application as fucosyltransferase substrates, both for mechanistic studies and in the chemoenzymatic synthesis of fluorine-containing oligosaccharides.

Efficient iodine-catalyzed preparation of benzylidene acetals of carbohydrate derivatives

An efficient preparation of benzylidene acetals of carbohydrate derivatives catalyzed by iodine has been developed. Yields were excellent in every case. Copyright Taylor & Francis Group, LLC.

The synthesis of β-mannopyranosides by intramolecular aglycon delivery: scope and limitations of the exciting methodology

The synthesis of β-mannopyrosides by intramolecular aglycon delivery is shown to proceed with complete stereoselectivity in six separate cases.This strategy has been successfully applied to the synthesis of several disaccharides, including octyl 3,6-di-O-