1616781-66-8

Basic information

• Product Name: 3-(diphenylphosphoryl)-1,2-bis(4-fluorophenyl)propan-1-one
• Synonyms: 3-(diphenylphosphoryl)-1,2-bis(4-fluorophenyl)propan-1-one
• CAS NO: 1616781-66-8
• Molecular Weight: 446.433
• Mol File: 1616781-66-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(diphenylphosphoryl)-1,2-bis(4-fluorophenyl)propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(diphenylphosphoryl)-1,2-bis(4-fluorophenyl)propan-1-one(1616781-66-8)
• EPA Substance Registry System: 3-(diphenylphosphoryl)-1,2-bis(4-fluorophenyl)propan-1-one(1616781-66-8)

Safety Data

• Hazardous Substances Data: 1616781-66-8(Hazardous Substances Data)

Upstream product

• 99734-06-2 α,α-bis(4-fluorophenyl)allyl alcohol 
• 4559-70-0 Diphenylphosphine oxide 

Relevant articles and documents

Eosin Y-catalyzed, visible-light-promoted carbophosphinylation of allylic alcohols via a radical neophyl rearrangement

A visible-light-promoted phosphinylation of allylic alcohols with concomitant 1,2-aryl migration is described. This transformation proceeds smoothly under metal-free and mild conditions by using an inexpensive organic dye, eosin Y, as the photocatalyst, affording various β-aryl-γ-ketophosphine oxides in moderate to good yields. Mechanistic studies suggested that the 1,2-aryl migration proceeded through a radical (neophyl) rearrangement.