1616868-85-9

Upstream product

• 1616868-88-2 C₉H₁₆O₂ 
• 1616868-89-3 (S)-2-((S)-1-(benzyloxy)hept-6-enyl)oxirane 
• 1616868-87-1 (4S,5S)-5-(benzyloxy)undeca-1,10-dien-4-ol 
• 100606-74-4 C₉H₁₆O 
• 158627-60-2 (E)-Nona-2,8-dienoic acid ethyl ester 
• 17206-61-0 hept-6-enal 
• 1616868-99-5 (2S,4S,6R)-2-((S)-1-(benzyloxy)hept-6-enyl)-6-((2R,5R)-5-((R)-1-(benzyloxy)tridecyl)-tetrahydrofuran-2-yl)-tetrahydro-2H-pyran-4-ol 
• 1616868-86-0 C₂₅H₄₀O₃ 
• 1616868-98-4 (S)-4-((2R,5R)-5-((R)-1-(benzyloxy)tridecyl)-tetrahydrofuran-2-yl)-2,2-dimethyl-1,3-dioxolane 
• 184435-68-5 (2R,5R,1'S,1R)-2-<1',2'-(1-methylethylidene)dioxy>-5-(1-hydroxytridecyl)tetrahydrofuran 
• 183308-65-8 (S)-2,2-Dimethyl-4-((2R,5R)-(R)-5-oxiranyl-tetrahydro-furan-2-yl)-[1,3]dioxolane 
• 1616868-97-3 C₁₈H₂₆O₇S 
• 4117-10-6 6-hepten-1-ol 
• 1616868-96-2 C₁₁H₂₀O₅ 

Relevant academic research and scientific papers

Stereoselective synthesis of tetrahydropyran-tetrahydrofuran (THP-THF) core of (+)-muconin via Prins cyclization

A stereoselective synthesis of tetrahydropyran-tetrahydrofuran (THP-THF) core 2 of (+)-muconin (1) has been achieved using Prins cyclization as a key step to construct tetrahydropyran moiety. Other important transformations such as Wittig olefination, Sharpless epoxidation, regio-, and stereoselective exo-cyclization of the epoxy alcohol, titanocene induced regioselective deoxygenation of 2,3-epoxy alcohol, Grignard reaction, and Barton-McCombie reaction are successfully employed to accomplish the synthesis of THP-THF core 2.