1616893-31-2Relevant academic research and scientific papers
Annulation of allylic phosphoryl-stabilized carbanions/phosphorus ylides and vinyl azides: A practice strategy for synthesis of polyfunctionalized anilines
Liu, Shen,Chen, Wenteng,Luo, Jing,Yu, Yongping
, p. 8539 - 8542 (2014)
Tandem Michael addition and Witting or Horner-Wadsworth-Emmons olefination initiated [3+3] annulation between vinyl azides and allylic phosphorus ylides or allylic phosphoryl-stabilized carbanions has been developed. This one-pot protocol furnishes highly functionalized anilines in good to excellent yields under mild, room-temperature conditions. A rational mechanism is also proposed. the Partner Organisations 2014.
