1616956-06-9Relevant academic research and scientific papers
CATALYTIC C-X-BOND METATHESIS THROUGH ARYLATION
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Page/Page column 21; 22, (2018/09/28)
The present invention refers to a process for a catalytic aryl transfer to rearrange the backbone of aromatic C-X bonds.
Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides
Guo, Sheng-Rong,He, Wei-Ming,Xiang, Jian-Nan,Yuan, Yan-Qin
, p. 8578 - 8581 (2014/07/22)
A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using di-tert-butyl peroxide (DTBP) as an oxidant catalyzed by Pd(OAc)2 has been reported. The C-H bonds in various alkanes or ethers were successfully converted into C-S bonds to yield the corresponding sulfides in moderate to good yields. the Partner Organisations 2014.
