161787-77-5

Basic information

• Product Name: [2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane
• Synonyms: [2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane
• CAS NO: 161787-77-5
• Molecular Weight: 337.581
• Mol File: 161787-77-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane(161787-77-5)
• EPA Substance Registry System: [2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane(161787-77-5)

Safety Data

• Hazardous Substances Data: 161787-77-5(Hazardous Substances Data)

Upstream product

• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 394739-08-3 bis[2,4,6-tris((dimethylamino)methyl)phenoxy]bis(trimethylsilyl)silane 
• 64-17-5 ethanol 

Relevant articles and documents

Some Aspects of Chemistry of the N->Si Chelated Aryloxydihydrosilanes R(ArO)SiH2(R = Ph, ArO) and of the 2,2-Diaryloxytrisilane (Me3Si)2Si(OAr)2{ArO = 2,4,6-[(CH3)2NCH2]3C6H2O}

Reactions of the pentacoordinate aryldioxydihydrosilane Ph(Ar)SiH2 (1) with hydroxyl groups, carbonyl derivatives and PCl5 resulted in formation of new alcoxylated, phenoxylated and halogenated hydrosilanes Ph(ArO)(H)X (X = Cl, OR, OAr, OC(O)R), respectively. Treatment of the hexacoordinated (4+2) diaryloxydihydrosilane (ArO)2SiH2 (2) with N-chloro- or N-bromosuccinimide, trimethylsilyltriflate or iodine yielded the novel stable silicenium ion [(ArO)2(H)Si](1+)X(1-). Reactions of 2 with sulfur S8 and the transition metal complex Fe(CO)5 have resulted in the isolation of the new complexes (ArO)2Si = E [E = S, Fe(CO)4]. Decomposition modes of the tetracoordinate 2,2-diaryloxytrisilane (Me3Si)2Si(OAr)2 (3) on thermolysis and photolysis have also been studied; two pathways involving formation of the two silylenes (ArO)(Me3Si): and (ArO)2Si: have been identified by trapping experiments