1618089-28-3

Basic information

• Product Name: 2,5-bis(hexyloxy)benzene-1,4-dithiol
• Synonyms: 2,5-bis(hexyloxy)benzene-1,4-dithiol
• CAS NO: 1618089-28-3
• Molecular Weight: 342.567
• Mol File: 1618089-28-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-bis(hexyloxy)benzene-1,4-dithiol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-bis(hexyloxy)benzene-1,4-dithiol(1618089-28-3)
• EPA Substance Registry System: 2,5-bis(hexyloxy)benzene-1,4-dithiol(1618089-28-3)

Safety Data

• Hazardous Substances Data: 1618089-28-3(Hazardous Substances Data)

Upstream product

• 128424-36-2 2,5-dihexyloxy-1,4-dibromobenzene 
• 111-25-1 1-bromo-hexane 
• 123-31-9 hydroquinone 

Downstream Products

• 1618089-29-4 S,S'-(2,5-bis(hexyloxy)-1,4-phenylene) O,O,O',O'-tetraisopropyldiphosphorothioate 
• 1618089-30-7 tetraisopropyl (2,5-bis(hexyloxy)-3,6-dimercapto-1,4-phenylene)bisphosphonate 
• 1618089-31-8 3,6-bis(hexyloxy)-1,4-dimercapto-2,5-diphosphinobenzene 
• 1618089-32-9 4,8-bis(hexyloxy)-2,6-diphenylbenzo[1,2-d:4,5-d']bis([1,3]thiaphosphole) 
• 1618089-35-2 4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole) 
• 1618089-36-3 4,4'-(4,8-bis(hexyloxy)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)-2,6-diyl)dibenzonitrile 

Relevant articles and documents

Tuning Thiophene with phosphorus: Synthesis and electronic properties of benzobisthiaphospholes

1,4-Dimercapto-2,5-diphosphinobenzene and 3,6-bis(hexyloxy)-1,4-dimercapto- 2,5-diphosphinobenzene were synthesized and combined with various acid chlorides to obtain a series of benzobisthiaphospholes. Electrochemical and photophysical properties of the substituted benzobisthiaphospholes have been evaluated, and the observed reductions are more facile than the related benzothiaphospholes and 2,6-diphenylbenzobisthiazole. A benzobisthiaphosphole with C6H 4-p-CN substituents was reduced at E1/2=-1.08 V (vs. saturated calomel electrode (SCE)). X-ray diffraction data for several of these phosphorus heterocycles has been obtained, and DFT calculations at the B3LYP level have been performed. Fused-ring systems: Energetic tuning of conjugated building blocks can be achieved by atomic modulation of aromatic architectures. A phosphorus mimic of benzodithiophene and benzobisthiazole has been synthesized and structurally characterized (see figure). The UV/Vis spectrum of the phosphorus heterocycle is significantly redshifted compared to its organic counterparts. The redox properties of the benzobisthiaphospholes have been probed and revealed reversible reductions in THF.