1618099-65-2Relevant academic research and scientific papers
Ruthenium-catalyzed one-pot synthesis of (E)-(2-arylvinyl)boronates through an isomerization/cross-metathesis sequence from allyl-substituted aromatics
Hemelaere, Remy,Caijo, Frederic,Mauduit, Marc,Carreaux, Francois,Carboni, Bertrand
, p. 3328 - 3333 (2014/06/09)
We described the efficient preparation of (E)-(2-arylvinyl)boronates from allylbenzene derivatives on the basis of an isomerization/cross-metathesis sequence catalyzed by a modified Hoveyda-Grubbs catalyst. The implementation of the experimental procedure was simple and compatible with a large variety of substrates. This methodology provides a new chemical transformation not described to date. Allyl-substituted aromatics can thus be converted into diversely functionalized compounds, such as (E)-stilbene derivatives or (E)-vinyl azides, in only two steps. Copyright
