161811-59-2

Basic information

• Product Name: 2-bromo-8-hydroxy-6-methylnaphthalene-1,4-dione
• Synonyms: 2-bromo-8-hydroxy-6-methyl-1,4-naphthoquinone; 2-Bromo-8-hydroxy-6-methylnaphthoquinone
• CAS NO: 161811-59-2
• Molecular Formula: C₁₁H₇BrO₃
• Molecular Weight: 267.0755
• Mol File: 161811-59-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 443.6°C at 760 mmHg
• Flash Point: 222.1°C
• Density: 1.785g/cm³
• Vapor Pressure: 1.75E-08mmHg at 25°C
• Refractive Index: 1.693
• CAS DataBase Reference: 2-bromo-8-hydroxy-6-methylnaphthalene-1,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-8-hydroxy-6-methylnaphthalene-1,4-dione(161811-59-2)
• EPA Substance Registry System: 2-bromo-8-hydroxy-6-methylnaphthalene-1,4-dione(161811-59-2)

Safety Data

• Hazardous Substances Data: 161811-59-2(Hazardous Substances Data)

Upstream product

• 120016-59-3 3-(hydroxymethyl)-5,8-dimethoxynaphthalen-1-ol 
• 101459-25-0 2-bromo-5,8-dimethoxy-3-methylnaphthalen-1-ol 
• 25932-95-0 Ethyl 4-(acetyloxy)-5,8-dimethoxy-2-naphthalenecarboxylate 
• 14787-38-3 7-methyljuglone 
• 50559-08-5 5,8-dimethoxy-3-methylnaphthalen-1-ol 
• 19643-45-9 2,6-dibromo-1,4-benzoquinone 
• 76915-33-8 (Z)-((1-methoxy-3-methylbuta-1,3-dien-1-yl)oxy)trimethylsilane 
• 73311-51-0 1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene 

Downstream Products

• 1227181-33-0 11-benzyloxy-1,9-dimethyl-6H-naphtho[2',3':4,5]furo[3,2-c]chromene-6,7,12-trione 
• 1309048-59-6 11-benzyloxy-4,9-dimethyl-6H-naphtho[2',3':4,5]furo[3,2-c]chromene-6,7,12-trione 
• 1227181-32-9 2-bromo-8-benzyloxy-6-methyl-1,4-naphthoquinone 

Relevant articles and documents

Total Synthesis of the Antitumor-Antitubercular 2,6′-Bijuglone Natural Product Diospyrin and Its 3,6′-Isomer

The 2,6′-bijuglone natural product diospyrin and its unnatural 3,6′-isomer idospyrin have been synthesized in seven steps each from N,N-diethylsenecioamide in overall yields of 12% and 13%, respectively. The syntheses diverge from ramentaceone (7-methylju

Synthesis of the reported structure of crassiflorone, a pentacyclic naphthoquinone isolated from the African ebony diospyros crassiflora

A short synthesis of the furocoumarin naphthoquinone structure reported for the natural product crassiflorone is described, in which the key steps are a Diels-Alder reaction to form 2-bromo-8-hydroxy-6-methylnaphthoquinone, followed by O-protection and co

Convergent total synthesis of the michellamines

The total synthesis of both michellamine A (1a) and B (1b), by consecutive construction first of the inner (non-stereogenic) axis and subsequently the two outer (stereogenic) axes in a highly convergent manner, is described. The michellamines are of consi