161868-41-3Relevant academic research and scientific papers
Phosphorylated hydrazines and aldehydes as precursors of phosphorus-containing multimacrocycles
Mitjaville, Jo?lle,Caminade, Anne-Marie,Daran, Jean-Claude,Donnadieu, Bruno,Majoral, Jean-Pierre
, p. 1712 - 1721 (1995)
Treatment of phosphodihydrazides PhP(Y)(N(CH3)NH2)2 (4a, Y = S; 4b, Y = O) with either the 3,3′-[(3-oxapentane-1,5-diyl)dioxy]bis(2-hydroxybenzaldehyde) (6) or 3,3′-[(3,6-dioxaoctane-1,8-diyl)dioxy]bis(2-hydroxybenzaldehyd
Synthesis and characterization of aminophosphines, bis(amino)phosphine derivatives, and their molybdenum(0) complexes
Sarioz, Oezlem,Serindag, Osman,Abdullah, Meysun I.
experimental part, p. 1785 - 1795 (2010/01/17)
Functionalized bis(amino)phosphines of the type PhP(NHR)2 (1a-c) and aminophosphines of the type Ph2PNHR (2a-c) have been synthesized by treating PhPCl2 or Ph2PCl with corresponding primary amines of H2N-R where R = -CH2SO3H, -C6H4SO3H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine (3) has been obtained by reacting cis-[Mo(CO)4(bipy)] with aminophosphine (2c). The synthesized aminophosphines, bis(amino)phosphines, and the molybdenum(0) complex have been characterized by IR, 1H NMR, 31P NMR, and MS spectroscopic techniques and by elemental analysis.
