1619936-06-9Relevant academic research and scientific papers
Rhodium-catalyzed direct coupling of biaryl pyridine derivatives with internal alkynes
Zheng, Jun,You, Shu-Li
, p. 8204 - 8207 (2014/07/21)
Axially chiral biaryls were synthesized by an isoquinoline or 2-pyridine-directed Rh(iii)-catalyzed dual C-H cleavage and coupling with internal alkynes in good to excellent yields. Oxidation of isoquinoline derivatives with m-CPBA furnished their corresponding N-oxides, which could be utilized as Lewis base catalysts in asymmetric reactions. This journal is the Partner Organisations 2014.
