1619971-24-2Relevant academic research and scientific papers
Direct Use of Benzylic Alcohols for Gold(III)-Catalyzed S-Benzylation of Mercaptobenzoic Acids in Water
Hikawa, Hidemasa,Tada, Ayaka,Kikkawa, Shoko,Azumaya, Isao
supporting information, p. 395 - 402 (2016/02/12)
We demonstrate the gold(III)-catalyzed direct substitution of benzylic alcohols in water. These atom economic and environmentally benign protocols afford S-benzylated products in moderate to excellent yields. In contrast, common Lewis or Br?nsted acids as
Cationic palladium(II)-catalyzed dehydrative nucleophilic substitutions of benzhydryl alcohols with electron-deficient benzenethiols in water
Hikawa, Hidemasa,Machino, Yumo,Toyomoto, Mariko,Kikkawa, Shoko,Azumaya, Isao
, p. 7038 - 7045 (2016/07/30)
An efficient direct nucleophilic substitution of benzhydryl alcohols with electron-deficient benzenethiols using cationic Pd(ii) catalysts as Lewis acids in water is reported. Atom economical and environmentally benign protocols afford S-benzylated produc
Mercaptobenzoic acid-palladium(0) complexes as active catalysts for S-benzylation with benzylic alcohols via (η3-benzyl)palladium(II) cations in water
Hikawa, Hidemasa,Azumaya, Isao
, p. 5964 - 5972 (2014/08/05)
Mercaptobenzoic acid-palladium(0) complexes show high catalytic activity for S-benzylation with benzylic alcohols via the (η3-benzyl) palladium(ii) cation in water. Notably, these palladium(0) complexes could play an important role in formation
