1620-03-7Relevant academic research and scientific papers
Electroreductive coupling of vinylpyridines and vinylquinolines: Radical anion-substrate cycloaddition?
Janssen, Robert G.
, p. 539 - 540 (2007/10/03)
Cathodic reduction of 2- and 4-vinylpyridine and of 2-vinylquinoline gives trans-1,12-di(heteroaryl)cyclobutanes as major products; they arise via radical anion-substrate cycloaddition.
FREE-RADICAL PYRIDYLETHYLATION OF ARYLALKANES
Galust'yan, G. G.,Il'yasov, E. A.,Kadyrov, Ch. Sh.
, p. 307 - 310 (2007/10/02)
2-(3-Arylpropyl)pyridines were synthesized in 30-54percent yields by the free-radical addition of toluene, o-, m-, and p-xylenes, and mesitylene to 2-vinylpyridine at 250-350 deg C.The products of rearrangement of the intermediate adduct radical with 1,3-H migration were isolated and identified.
