16200-57-0

Upstream product

• 768-93-4 1-iodoadamantane 
• 16836-95-6 silver(I) 4-methylbenzenesulfonate 
• 768-95-6 1-adamanthanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 768-90-1 1-Adamantyl bromide 
• 876-53-9 1,3-dibromoadamantane 
• 19158-51-1 P-toluenesulfonyl cyanide 

Downstream Products

• 6221-74-5 1-methoxyadamantane 
• 38614-05-0 (3s,5s,7s)-1-phenoxyadamantane 
• 38614-06-1 2-((3r,5r,7r)-adamantan-1-yl)phenol 
• 79621-74-2 1-(4-phenoxybutoxy) adamantane 
• 112543-88-1 1-Adamantan-1-yl-2,4,6-triphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine 
• 85963-94-6 triphenylverdazylium p-toluenesulfonate 
• 935-56-8 1-chloroadamantane 
• 768-95-6 1-adamanthanol 
• 281-23-2 adamantane 
• 880-52-4 N-(1-adamantyl)acetamide 
• 85963-93-5 2,4,6-triphenyl-1--1,2,3,4-tetrahydro-1,2,4,5-tetrazine 
• 22459-57-0 2,4,6-triphenylverdazyl 
• 17127-02-5 2,4-diphenyl-6-(4-methoxyphenyl)leucoverdazyl 
• 57020-66-3 6-(4-nitro-phenyl)-2,4-diphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine 

Relevant academic research and scientific papers

Carbon glucoside sodium glucose transport protein body 2 inhibitor

The invention relates to a carbon glucoside sodium glucose transport protein body 2 inhibitor, a preparation method and an application of the inhibitor. The carbon glucoside sodium glucose transport protein body 2 inhibitor has a structure as shown in general formula (I) as shown in the specification.

Solvent-free and selective tosylation of alcohols and phenols with p-toluenesulfonyl chloride by heteropolyacids as highly efficient catalysts

Tosylation of some alcohols and phenols has been directly carried out with p-toluenesulfonyl chloride using heterodoxy acids (H3PW 12O40, H3PMo12O40, A 3PW12O40, and AlPMo12O40) as catalysts in the absence of solvent. We found that heteropoly acids AlPW12O40 and AlPMo 12O40 were effective catalysts for the tosylation of alcohols and phenols. In the case of aliphatic alcohols, secondary alcohols undergo tosylation chemoselectively in the presence of primary hydroxyl groups. This new method consistently has the advantage of excellent yields and short reaction time.

O-Sulfinylation of alcohols with methanesulfonyl cyanide or p-toluenesulfonyl cyanide

Reaction of p-toluenesulfonyl cyanide or methanesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]under-7-ene (DBU) or 1,4-diazabicyclo[2.2.2]octane (DABCO) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates 9 and 21 is suggested.

Herstellung und Solvolyse von 3-substituierten p-Toluolsulfonsaeure-(1-adamantyl)estern

Methods for the preparation of some hitherto unknown 3-substituted 1-adamantyl toluenesulfonates are evaluated.Their solvolysis products in dioxane/water 70:30 are reported.