1620057-23-9

Basic information

• Product Name: bis(2-methoxyphenyl)(phenyl)(o-tolylethynyl)phosphonium bromide
• CAS NO: 1620057-23-9
• Molecular Weight: 517.402
• Mol File: 1620057-23-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(2-methoxyphenyl)(phenyl)(o-tolylethynyl)phosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2-methoxyphenyl)(phenyl)(o-tolylethynyl)phosphonium bromide(1620057-23-9)
• EPA Substance Registry System: bis(2-methoxyphenyl)(phenyl)(o-tolylethynyl)phosphonium bromide(1620057-23-9)

Safety Data

• Hazardous Substances Data: 1620057-23-9(Hazardous Substances Data)

Upstream product

• 578-57-4 2-bromoanisole 
• 644-97-3 Dichlorophenylphosphine 
• 72591-20-9 1-bromo-2-(ortho-methylphenyl)ethyne 
• 36802-41-2 bis-(2-methoxy-phenyl)-phenyl-phosphane 

Downstream Products

• 136053-56-0 1,4-di-(o-tolyl)buta-1,3-diyne 
• 1620057-32-0 (Z)-2,2',2''-(hexa-3-en-1,5-diyne-1,3,6-triyl)tris(methylbenzene) 

Relevant articles and documents

A phosphine-mediated stereocontrolled synthesis of Z-enediynes by a vicinal dialkynylation of ethynylphosphonium salts

Z-Enediynes are prepared by a vicinal dialkynylation of triaryl(arylethynyl)phosphonium cations. The method, which proceeds under mild transition metal-free conditions, can be conducted on multigram scale as a one-pot, phosphine-mediated synthetic cycle giving enediyne products with excellent control of configuration.