1620086-87-4Relevant academic research and scientific papers
Efficient asymmetric syntheses of 1-phenyl-phosphindane, derivatives, and 2- or 3-oxa analogues: Mission accomplished
Rast, Slavko,Mohar, Barbara,Stephan, Michel
, p. 2688 - 2691 (2014)
A highly enantioselective synthesis of unsubstituted 1-phenyl-phosphindane and its P-borane and P-oxide derivatives was effectively established via a new fluoride-triggered desilylative carbocyclization strategy. Preparation of the oxygen atom-doped 1-phenyl-3-oxa-1-phosphindane-P-borane analogue was otherwise achieved via a tandem P-α-iodination-intra-O-alkylation.
