1620109-72-9Relevant academic research and scientific papers
Syntheses and characterization of palladium(II) complexes with a bidentate bis-NHC ligand having methyl and aryl substituents on terminal nitrogen atoms
Yagyu, Takeyoshi,Tsubouchi, Ayana,Nishimura, Yuki
, p. 1 - 5 (2014)
An imidazolium salt, N-chloromethyl-N′-methylimidazolium bromide was prepared as an intermediate for the syntheses of unsymmetrical bidentate bis-NHC ligands bearing methyl and aryl substituents on the terminal nitrogen atoms. Three bis-NHC ligand precursors and their corresponding palladium(II) complexes were also prepared. 1H NMR spectra of the imidazolium salts of the bidentate ligands implied that the carbene on a methyl-substituted imidazolylidene ring is a stronger donor than one on an aryl-substituted ring. The crystal structures of the palladium(II) complexes showed a distorted square-planar structure. The complexes demonstrated good catalytic performance in the Heck reaction.
